Self-assembly of a covalent organic cage with exceptionally large and symmetrical interior cavity: the role of entropy of symmetry.
نویسندگان
چکیده
An exceptionally large size cuboctahedral imine cage is obtained from small size organic molecules in a thermodynamically driven [8+12] cyclocondensation. This is a demonstration of the role of entropy of symmetry as a driving force in reversible reactions.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 25 شماره
صفحات -
تاریخ انتشار 2013